A 3.00 g sample containing `Fe_3O_4, Fe_2O_3` and an inert impure substance, is treated with excess of KI solution in pr

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Q 1159167914.     A 3.00 g sample containing `Fe_3O_4, Fe_2O_3` and an inert impure substance, is treated with excess of KI solution in presence of dilute `H_2SO_4`. The entire iron is converted into `Fe^(2+)` along with the liberation of iodine. The resulting solution is diluted to 100 mL. A 20 mL of the diluted solution requires 11.0 mL of 0.5 M `Na_2S_2O_3` solution to reduce the iodine present. A 50 mL of the dilute solution, after complete extraction of the iodine required 12.80 mL of 0.25 M `KMnO_4` solution in dilute `H_2SO_4` medium for theoxidation of `Fe^(2+)`. Find the percentage of `Fe_2O_3` and `Fe_3O_4` in the original sample respectively.


JEE 1996
A

`44.12 % , 34.80 %`

B

`49.33 % , 34.80 %`

C

`49.33 % , 28.10 %`

D

`44.12 % , 28.10 %`

HINT


Solution
(Provided By a Student and Checked/Corrected by EXXAMM.com Team)

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