Chemistry WEAK AND STRONG ELECTROLYTES

Electrolytes-Introduction

Substance which can conduct electricity either in their aqueous or molten state. It has following properties :

When an electrolyte is dissolved in a solvent (usually water) or is fused, it spontaneously dissociates into oppositely charged particles called ions, to a considerable extent.

`H_2SO_4 ⇋ 2H^+ +SO_4^(2-)`

The positively charged ions are called cations and the negatively charged ions are called anions.

Electrolytes-Types of Electrolytes

Strong Electrolytes: These are the substances which when dissolved in water (solvent) dissociates completely into ions.
ex- `NaCl ⇋ Na^(+)+Cl^(-)`

Weak Electrolytes:These are the substances which when dissolved in water (solvent) dissociates partially into ions.
ex- `CH_3COOH ⇋ CH_3COO^(-)+H^(+)`

Factors affecting Degree of Dissociation(``) -Nature of the electrolyte

Some electrolytes, e.g., mineral acids such as `H_2SO_4, HCl` and `HNO_3`, alkalis such as `NaOH` and `KOH` and all salts have a very high degree of ionization (`alpha` nearly equal to `1`) at all reasonable concentrations. They are known as strong electrolytes. The number of ions in solutions of strong electrolytes is large and thus such solutions have high conductance.

Some electrolytes, e.g., organic acids such as acetic acid, propionic acid. etc., and bases like ammonium hydroxide have a low degree of ionization in solution. They are called weak electrolytes. The number of ions in solutions of weak electrolytes is quite small and thus such solutions have low conductance.

Factors affecting Degree of Dissociation(``)-Nature of the solvent:

A solvent which has a high dielectric constant weakens the attractive force between the cations and anions. Hence a solvent of high dielectric constant favours the dissociation of the electrolyte. Likewise a solvent which can solvate the ions readily, and can release energy by solvation, favours the dissociation of the electrolyte. Thus, the dissociation of acids in water is favoured by the hydration of the hydrogen ions to form hydronium ions. The enthalpy of hydration of the proton has a very high value.

Factors affecting Degree of Dissociation(``)-Dilution:

For some electrolytes, degree of dissociation increases with dilution as explained by Ostwald's dilution law (will beexplained later).

Factors affecting Degree of Dissociation(``)-Temperature:

Increase of temperature generally increases ionization.

 
SiteLock