Chemistry ACID-BASE EQUILIBRIUM

Ostwald's Dilution Law

This law deals with the application of the law of mass action to the equilibrium between the ions and unionized molecules in aqueous solutions of weak binary electrolytes such as acetic acid, propionic acid, `HCN, NH_4OH`, etc.

Consider a dilute solution of a weak binary electrolyte `AB` containing `c` moles in `1` litre.

At any given temperature, there will be equilibrium between the unionized molecules of `AB` and the ions `A^+` and `B^-` . let `'alpha'` be the degree of dissociation of `AB` at equilibrium.

`AB ⇋ A^(+)+B^(-)`

Indicators

According to Ostwald Theory of acid-base indicator, an acid-base indicator is a weak organic acid or weak organic base which remains partially dissociated/protonated in aqueous solution and of which, ionised and unionised forms possess different colour. If `Hln` be an indicator (a weak acid) then its dissociation may be represented as:

`underset(Acid A) (HIn) -> H^(+) + underset (Base B)(In^(-))`

The dissociation constant of an acid indicator is called indicator constant and is denoted by the symbol `K_(I n)`,

 
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