Chemistry NATURE OF ELECTROMAGNETIC RADIATION

Characteristics of Waves :

A wave is a sort of disturbance which originates from some vibrating source and travels outward as a continuous sequence of alternating crests and troughs. Every wave has five important characteristics, namely, wavelength (l), frequency (n), velocity (C), wave number `(barv)` and amplitude (`A`). See fig.

Ordinary light rays, `X`- rays, `gamma`-rays etc. are called electromagnetic radiations because similar waves can be produced by moving a charged body in a magnetic field or a magnet in an electric field. These radiations have wave characteristics and do not require any medium for their propagation.

i) `text(Wave length)` `(l)` : The distance between two neighbourinq troughs or crests is known as wavelength. It is denoted by `l` and is expressed in `cm`, `m`, nanometers (`1` nm=`10^(-9)` m). or Angstrom (`1 overset(o)(A) =10^(-10)m`); 1 micron `(mu)= 10^(-6)m, 1` milli micron `(mmu)` `=10^(-9), 1 p m = 10^(-12)` m.

ii) `text(Frequency) (nu)` : The frequency of a wave is the. number of times a wave passes through a given point in a medium in one second. It is denoted by `(nu)` and is expressed in cycles per second (cps) or hertz (Hz). 1 Hz = 1 cps.

The frequency of a wave is inversely proportional to its wave length (`l`). `n prop 1/ lambda` or `n = c/lambda`

iii) `text(Velocity)` : The distance travelled by the wave in one second is called its velocity. It is denoted by `c` and is expressed in `cm``text(sec)^(-1). `c` = `n l`` or `l = c/lambda`

iv) `text(Wave number) (barnu)` : It is defined as number of wavelengths per `cm`. It is denoted by `(bar nu)` and is expressed in `cm^(-1)`. `barnu = 1/ lambda ` (or) `barnu = v/c`

v) `text(Amplitude)` : It is the heiqht of the crest or depth of the trough of a wave and is denoted by `a`. It determines the intensity or brightness of the beam of light & is also expressed in the unit of length.

Electromagnetic Waves :

Wave theory was given by C. Huygens. In `1856`, James Clark Maxwell stated that light, `X`-rays, `gamma`-rays and heat etc. emit energy continuously in the form of radiations or waves and the energy is called radiant energy. These waves are associated with electric and magnetic fields and are, therefore, known as electromagnetic waves (or radiations). A few important characteristics of these waves are listed :

(i) They emit energy continuously in the form of radiations or waves.

(ii) The radiations consist of electric and magnetic fields which oscillate perpendicular to each other and also perpendicular to the direction in which the radiations propagate.

(iii) All the electromagnetic waves travel with the velocity of light `(3.0 xx 10^8 ms^(-1))`

(iv) These rays do not require any medium for propagation.

(v) They are not affected by electric or magnetic fields.

Wavelength of Electromagnetic Radiations :

The complete range of the electromagnetic waves is known as electromagnetic spectrum. It may be defined as : The arrangement of different electromagnetic radiations in order of increasing wavelength or decreasing frequency. See fig.

 
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