Chemistry HYDRATION ENERGY

Hydration Energy :

When a gaseous cation or gaseous anion interacts with water, hydrated cation or hydrated anion is produced and in this process (called hydration process), the energy released is called as hydration energy.

`M_g^(+) + (H_2O)_(l) -> undersettext(Hydrated cation)(M_(aq)^(+)) + text(Hydration energy)`

`X_g^(-) + (H_2O)_(l) -> undersettext(Hydrated cation)(X_g^(-)) + text(Hydration energy)`

Hydration energy is the enthalpy change that accompanies when one mole of the gaseous ion is dissolved in water.

For example, reaction of the hydration of `Li` ion is shown as :

`Li^(+) (g) + nH_2O -> Li(H_2O)_n(aq); Delta H = - 806 kJ text(mol)^(-1)`.

The process by which polar water molecules clings (sticks) to `Na^+` and `Cl^-` is called hydration. Ions are converted to hydrated form.

`text(Hydration energies (heat of hydration)` `text(of some ions)` : `(kJ//mol)`. See Table.

Factors Affecting Hydration Energy :

`text(Size of Gaseous Ion)` : As the size of gaseous ion will increase the hydration energy will decrease. This is because more concentrated charge means more hydration energy.

`text(Charge on Ion)` : As the charge increases there would be more attraction for water molecules & hence hydration energy will increase, provided size does not increase significantly.

`text(Hydration energy) prop text(Charge on the ion))/text(size of the ion)`


 
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